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Once you have your Kindle connected to your computer, if you already have Calibre up and running, you will see the tool bar change. It knows when there is a Kindle connected and there are a couple of extra buttons to help you with various tasks.
If you have your Kindle connected, you can quickly switch between the Library and the Device button to see a list of books. The Library shows what is on your computer. If anything listed is also on your connected Kindle, you will see a check mark next to it.
Click the Device button to see the books on your connected Kindle listed. Any books with a check mark next to them are also on your computer hard drive in the Library. I discovered (quite by accident) that if you right click any of the books listed on your Kindle, you can choose to have a copy of the book sent to your Library on your computer. How about that for an interesting, no fuss way to back up the books on your Kindle?
Stay tuned...